Ibicuruzwa

Inshuro eshatu zinyeganyezwa zine-zivanga spekitroscopi ikoreshwa kugirango harebwe ihererekanyabubasha hagati ya asimmetric na symmetric CO-kurambura uburyo bwa rhodium (I) dicarbonyl acetylacetonate (RDC).Kwimura kwa Coherence ninzibacyuho idahwitse yimiterere ya kwant ya reta kumiterere itandukanye ihuriweho bitewe no guhuza uburyo bwo kunyeganyega binyuze mubwogero.Byose uko ari bitatu byishimishije mubigeragezo birumvikana hamwe na kwant imwe imwe, ariko ihererekanyabubasha rivamo ibisubizo bishya hamwe numurongo utandukanye.Ibisohoka bishya bigaragarira hamwe na monochromator ikemura uhereye kumpera ikomeye kumurongo wambere wibyishimo.Ubu buhanga bukemura inzira zirimo kwimura coherence, kuvangura ibintu byerekanwe byakozwe gusa ninzibacyuho yimirasire, kandi bigakemura byigihe gito impinduka zatewe no kwivanga hagati yinzira zitandukanye zo kwimura.Redfield théorie simu itinda ihinduka ryigihe gito mumipaka itabishaka, ariko nanone biragaragara ko ihererekanyabubasha ryica ikigereranyo cyisi cyasabwe mubitekerezo byinshi bya Redfield.Ahubwo, bisaba ingaruka zitari Markovian hamwe no kwiyuhagira.RDC irashobora gutanga icyitegererezo cyoroshye mugutezimbere ibitekerezo bikubiyemo izi ngaruka.