Pentamethylcyclopentadienyltris (acetonitrile) ruthenium (II) hexafluorophosphate Cas: 99604-67-8 Ifu yumuhondo Orange
Umubare wa Cataloge | XD90827 |
izina RY'IGICURUZWA | Pentamethylcyclopentadienyltris (acetonitrile) ruthenium (II) hexafluorophosphate |
URUBANZA | 99604-67-8 |
Inzira ya molekulari | C16H24F6N3PRu |
Uburemere bwa molekile | 504.42 |
Ibisobanuro birambuye | 2-8 ° C. |
Kugaragaza ibicuruzwa
Kugaragara | Ifu y'umuhondo |
Suzuma | 99% |
Urusobekerane [Cp * Ru (MeCN) 3] PF6 yerekanwe guhagarika hydrosilylation ya alkine nyinshi.Terminal alkynes itanga uburyo bwo kubona ibicuruzwa bya alpha-vinylsilane hamwe na regioselectivite nziza.Ubushakashatsi bwa Deuterium bwerekana inzira isukuye yongeyeho.Urusobekerane rumwe rukora muri alkyne hydrosilylation y'imbere, aho guhitamo byimazeyo inzira yo kongera inzira bikomeza.Ibyiciro byinshi byimbere ya alkyne imbere, harimo alcool ya propargylic na alfa, beta-alkynyl ya karubone, itanga vinylsilane ya regioselective.Kwihanganira ibintu byinshi bya silan birashimishije, harimo alkyl-, aryl-, alkoxy-, na halosilanes.Iyi nyungu igaragarira muri synthesis itaziguye ya triene substrate ya silicon-ihujwe na intramolecular Diels-Alder cycloadditions.